Depends on what sort of post-apocalypse your story takes place in -- or, conversely, what sort of feeling you want.
For a colder, more rural apocalypse -- Cormac McCarthy's The Road kind of stuff -- I'd have to recommend Current 93 (especially Black Ships Ate the Sky, and particularly Bonnie "Prince" Billy's version of "Idumæa." Other good music along those lines: Sol Invictus' Against the Modern World, Agalloch's The Mantle and Ashes Against the Grain (if you've a tolerance for death-metal-ish vocals).
Tori Amos' cover of "Raining Blood" works well for this kind of thing, too.
If you've got a more of a sci-fi/cyberpunk future, I'd highly recommend Killing Joke's catalogue. Like, pretty much all of it. Very dark, dirty, ugly, tribal industrial-punk stuff that's perfect for conjuring up spiky-haired gangs roaming the garbage-strewn streets of a post-industrial futuristic dystopia. The Sisters of Mercy's Floodland -- along with the singles collected on Some Girls Wander by Mistake -- would also slot in well here.
And if it's more of an Orwellian, futuristic-fascist state you're in the market for: Arcade Fire's Neon Bible.
Yeah, I've spent a lot of time plotting and scoring apocalypses.
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